AP Exam Prep · AP Chemistry

AP Chemistry Unit 6 Practice Test: Thermochemistry

Unit 6 tracks energy in physical and chemical changes. You will calculate heat with q = mcΔT, find enthalpy changes from bond enthalpies, formation data and Hess's law, and read energy diagrams.

Exam weighting:
7–9%
Questions:
12 multiple choice
Time:
about 16 minutes
Cost:
Free, no sign-up

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Question 1 of 12 · 0 answered

Question 1

Topic 6.1 · Apply it

When ammonium nitrate dissolves in water in a cold pack, the pack gets cold. Which statement is correct?

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What AP Chem Unit 6 covers

Unit 6, Thermochemistry, makes up 7–9% of the multiple-choice section and usually takes ~10–11 class periods. These are the topics in the current course framework, and every question in the test above is tagged with one of them.

  1. 6.1Endothermic and Exothermic Processes
  2. 6.2Energy Diagrams
  3. 6.3Heat Transfer and Thermal Equilibrium
  4. 6.4Heat Capacity and Calorimetry
  5. 6.5Energy of Phase Changes
  6. 6.6Introduction to Enthalpy of Reaction
  7. 6.7Bond Enthalpies
  8. 6.8Enthalpy of Formation
  9. 6.9Hess's Law

Unit 6 key ideas

Exothermic and endothermic

Exothermic processes release energy to the surroundings (ΔH < 0); endothermic processes absorb it (ΔH > 0). Breaking bonds always requires energy; forming bonds releases it.

Calorimetry

q = mcΔT. In a calorimeter, heat lost by one part equals heat gained by the other, so the temperature change of water can reveal the heat of a reaction.

Three ways to find ΔH

Use bond enthalpies (bonds broken − bonds formed), enthalpies of formation (products − reactants) or Hess's law (combine reactions, flipping signs and scaling as needed).

Phase changes

During melting or boiling, added energy overcomes intermolecular forces, so temperature stays constant until the change is complete.

Common Unit 6 mistakes

  • Reversing the order in bond-enthalpy calculations (it's broken − formed).
  • Forgetting to flip the sign when reversing a reaction in Hess's law, or to scale ΔH with coefficients.
  • Mixing up the system and the surroundings when deciding the sign of q.

How to study this unit

  • Write which way heat flows (system → surroundings or the reverse) before choosing a sign.
  • Keep a one-line rule for each ΔH method and check which data the question gives you.

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About these questions

StudyCoach wrote these questions for this test. Each one is mapped to a topic in the College Board's current AP Chemistry course framework. Every answer key was also checked by a separate AI review, and any disagreement was rechecked by hand. They have not yet been reviewed by an AP Chemistry teacher. If you think an answer is wrong, email support@studycoach.io.

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